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Pearl Sullivan Professor and Chair, Department of Mechanical and Mechatronics Engineering |
Laboratories:
Composites and Adhesives Lab
Research Interests:
Advanced Polymers and Composites, Micro-Engineering, Adhesive Bonding, Smart Structures
(i) Polymers and their Composites
Although polymers and their composites are increasingly becoming the mainstream materials in engineering design, their long-term stability under combined thermo-mechanical loads is still not well characterized. This is because the response of these materials evolve over time for two reasons: (i) their inherent molecular structure leads to mechanical properties that are viscoelastic, i.e. time- and temperature-sensitive; and (ii) the release of residual stresses formed during high volume manufacturing, such as injection molding, resulting in dimensional changes. Both effects can profoundly affect the integrity and performance of the part. More important, with the growing trend towards miniaturization in advanced technologies, polymeric products are increasingly smaller with thinner walls. Innate volumetric changes in these small parts pose problems especially in tight-tolerance applications as they lead to part warpage.
This research program involves the characterization and modeling of the thermo-mechanical behaviour of a wide spectrum of polymer-based materials ranging from structural adhesives used in building high performance aircraft to thermoplastic welds in optoelectronics packaging. The developed constitutive models are then implemented into a commercial finite element analysis (FEA) package to enable the designer to predict part performance. An emerging area from this core research capability is related to micro-engineering which aims to model the divergence of thermo-mechanical properties from their bulk values as dimensions are reduced.
(ii) Adhesive bonding of dissimilar joints
One of the major technical challenges in using different materials to fabricate engineering structures is how to join them. This research specifically addresses the emerging problem in aerospace, automotive and electronics applications where lightweight, high-stiffness and strong polymeric composites are increasingly being used to replace metals. Recent projects include the repair of aging aircraft that involves designing a process for adhesively bonding a carbon-fibre composite component onto the metallic parent structure. There is interest in extending this technology for the development of lightweight wind turbines.
(iii) Development of smart structures
The smart structures program is strongly coupled with both the composites and adhesive bonding programs. The concept of applying in-situ health monitoring technology within engineering structures is very attractive from a maintenance standpoint. Recent work has embedded a distributed fiber optic sensor within laminated composite materials for cure monitoring as a first step for developing a passive smart structure. Future work will extend this embedded sensing capability for damage detection within the structure when subjected to external loading as well as evaluate the capabilities of new film sensors.
Journal Publications
Dasappa P, Lee-Sullivan P and Xiao X, Development of viscoplastic strains during creep incontinuous fiber GMT composites, Composites Part B: Engineering, 2009, in press.
Dasappa P, Lee-Sullivan P and Xiao X, Temperature effects on creep behavior of continuous fiber GMT composites, Composites Part A: Applied Science and Manufacturing, 2009, in press.
Haghighi Yazdi, M., and Lee-Sullivan, P., Determination of dual glass transition temperatures of a PC/ABS blend using two TMA modes, Journal of Thermal Analysis and Calorimetry, Vol 96 (1), 2009, 7-14.
Tang, J.K.Y. and Lee-Sullivan, P., Observations of physical aging in a polycarbonate and acrylonitrile-butadiene-styrene (PC/BS) blend, Journal of Applied Polymer Science, Vol 10 (1), Oct 2008, pp. 97-108
Dasappa, P., Lee-Sullivan, P., X. Xiao and P. Foss, Tensile creep of a long-fibre glass mat GMT thermoplastic. Part II – Viscoelastic-viscoplastic constitutive model, Polymer Composites, accepted March 2008
Dasappa, P., Lee-Sullivan, P., X. Xiao and P. Foss, Tensile creep of a long-fibre glass mat GMT thermoplastic. Part I – Short-term tests, Polymer Composites, accepted March 2008
LaPlante, G., Ouriadov, A.V., Lee-Sullivan, P. and Balcom, B., Anomalous moisture diffusion in an epoxy adhesive detected by Magnetic Resonance Imaging, Journal of Applied Polymer Science, Vol . 109 (2), pp. 1350-1359, 2008
A. Law, L. Simon and Lee-Sullivan, P., Effects of thermal aging on isotactic polypropylene crystallinity, Polymer Engineering and Science, Vol. 48 (4), pp 627–633, 2008
Lee-Sullivan, P., Influence of cooling rate on the stress relaxation response of strained piezoelectric PVDF film, Materials Research Innovations, Vol. 10(4), Dec 2006.
Li, G. and Lee-Sullivan, P., Re-visiting the beam models for adhesively bonded single-lap joints. Part I: Comparison of bending moment predictions, Canadian Aerospace and Space Institute Journal, Vol.52 (4), pp.149 -171, 2006
Li, G. and Lee-Sullivan, P., Re-visiting the beam models for adhesively bonded single-lap joints. Part II: Comparison of bending moment predictions, Canadian Aerospace and Space Institute Journal, Vol.52 (4), pp.173 -180, 2006
Lee-Sullivan, P. and Bettle, M.**,Comparison of enthalpy relaxation between two different molecular masses of a bisphenol-A polycarbonate, J. Thermal Analysis and Calorimetry, Vol. 81, 2005, 169-177 .
LaPlante, G., Ouriadov, A., Balcom, B.J. and Lee-Sullivan, P., Anomalous moisture diffusion in an epoxy adhesive detected by Magnetic Resonance Imaging, in print, J. Applied Polymer Science, 2005 .
LaPlante, G., Marble, A., MacMillan, A., Lee-Sullivan, P., Colpitts, B.G. and Balcom, B.J.,
Detection of water ingress in composite sandwich structures: a magnetic resonance approach, Non-Destructive Testing and Evaluation, 38, 2005, 501-507 .
LaPlante, G., Ouriadov, A.V., Lee-Sullivan, P. and Balcom, B.J., Anomalous moisture diffusion in an epoxy adhesive detected by magnetic resonance imaging, in print, J. Applied Polymer Science, 2005 .
Marble, A., Mastikin, I.V., MacGregor, R., Akl, M., LaPlante, G., Colpitts, B.G., Lee-Sullivan, P., and Balcom, B., Distortion free single point imaging of multi-layered composite sandwich panel surfaces, Journal of Magnetic Resonance, 168, 2004, pp. 164-174 .
Rogers, A. and Lee-Sullivan, P., An alternative cure kinetics model for a high temperature film adhesive, Polymer Engineering and Science, Vol. 43(1), 2003, pp. 14-25
Lee-Sullivan, P., Dykeman, D. and Qing, S., Mechanical relaxations in heat-aged polycarbonate. Part I - Comparison between two molecular weights, Polymer Engineering and Science, Vol. 43(2), 2003,pp. 369-382
Dykeman, D. and Lee-Sullivan, P., Mechanical relaxations in heat-aged polycarbonate. Part II - Statistical analysis of low molecular weight data, Polymer Engineering and Science, Vol. 43(2), 2003, pp. 383-398